Abstract

The decomposition of metal (Ti, Zr, Sn) alkoxides at 250 degrees C in a solution of tetradecene and dodecylamine resulted in the formation of ultra-small (1-2 nm) oxide nanoparticles. The nanoparticles showed unusual structural properties. The high-pressure orthorhombic phase was found for SnO2. The as-synthesized ZrO2 nanoparticles were only partially crystallized. It was possible to observe their in situ crystallization under the TEM beam. The TiO2 nanoparticles appeared amorphous, with only a few nanocrystals dispersed in the sample. The temperature evolution of the samples was investigated in situ by Raman spectroscopy. All SnO2 was converted to stable cassiterite at 350 degrees C. TiO2 and ZrO2 samples displayed phase stability reversal over a broad range of temperatures.

Autore Pugliese

• Epifani Mauro Salvatore

Tutti gli autori

• Epifani M.; Arbiol J.; Pellicer E.; Sergent N.; Pagnier T.; Morante J.R.

Titolo volume/Rivista

Materials chemistry and physics

Anno di pubblicazione

2010

ISSN

0254-0584

ISBN

Non Disponibile

Numero di citazioni Wos

Nessuna citazione

Ultimo Aggiornamento Citazioni

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Numero di citazioni Scopus

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Ultimo Aggiornamento Citazioni

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Settori ERC

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Codici ASJC

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