Abstract

Functionalization with fluorine atoms represents a versatile structural modification tofinely tune both the emission colour and the electronic properties of organic and organometallicelectroluminescent compounds. This paper reports an overview of our systematic investigation onthe design and synthesis of the fluorinated version of two important classes of materials for organiclight emitting diodes (OLEDs), namely poly(arylenevinylene)s and phosphorescent phenylpyridineIridium complexes. Synthetic pathways based on organometallic methodologies affordingselectively fluorinated molecular structures will be discussed together with a summary of the effectof fluorination on the optical properties of the resulting materials. In particular we will highlight thepossibilities offered by the organometallic methodologies as straightforward and resourceful toolsto provide a wide series of fluorinated molecular architectures with high regio- andstereoselectivity, mild experimental conditions and good yields.

Autore Pugliese

• Cardone Antonio , Hassan Omar Omar

Tutti gli autori

• Farinola G. M.; Babudri F.; Cardone A.; Hassan Omar O.; Martinelli C.; Naso F.; Pinto P.; Ragni R.

Titolo volume/Rivista

Advances in science and technology

Anno di pubblicazione

2010

ISSN

1662-0356

ISBN

Non Disponibile

Numero di citazioni Wos

Nessuna citazione

Ultimo Aggiornamento Citazioni

Non Disponibile

Numero di citazioni Scopus

Non Disponibile

Ultimo Aggiornamento Citazioni

Non Disponibile

Settori ERC

Non Disponibile

Codici ASJC

Non Disponibile