Abstract

In this paper, we describe the synthesis and the electronic properties of a series of [Cu(NN)2]+ systems. The NN ligands investigated are 2,9-bis[(tert-butyldimethylsilyloxy)methyl]-1,10-phenanthroline (1), 2,9-bis[(triisopropylsilyloxy)methyl]-1,10-phenanthroline (2), 2,9-bis[(tert-butyldiphenylsilylmoxy)ethyl]-1,10-phenanthroline (3), 2,9-bis[2,6-bis(benzyloxy)phenethyl]-1,10-phenanthroline (4) and 2-(1,3-diphenylpropan-2-yl)-9-phenethyl-1,10-phenanthroline (5). The electrochemical properties and the ground state electronic absorption spectra of Cu(1)2-Cu(5)2 are in line with the classical behaviour of such [Cu(NN)2]+ derivatives. Whereas all the compounds exhibit MLCT luminescence centered around 630-650 nm, the emission quantum yields and the lifetimes are dramatically different as a function of stereoelectronic effects and/or the possibility of internal exciplex quenching when oxygen-containing functional groups are attached to the phenanthroline ligands.

Autore Pugliese

• Accorsi Gianluca

Tutti gli autori

• G. Accorsi; N. Armaroli; C. Duhayon; A. Saquet; B. Delavaux-Nicot; R. Welter; O. Moudam; M. Holler; J.-F. Nierengarten

Titolo volume/Rivista

European journal of inorganic chemistry

Anno di pubblicazione

2010

ISSN

1434-1948

ISBN

Non Disponibile

Numero di citazioni Wos

Nessuna citazione

Ultimo Aggiornamento Citazioni

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Numero di citazioni Scopus

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Ultimo Aggiornamento Citazioni

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Settori ERC

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Codici ASJC

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