Red-emitting AIEgen for luminescent solar concentrators
Abstract
This study reports for the first time the use of a red-emitting AIEgen, i.e. TPE-AC, for the realization of efficient luminescent solar concentrators (LSCs) based on poly(methyl methacrylate) (PMMA) and polycarbonate (PC) thin films (25 +/- 5 mu m). TPE-AC is an AIEgen with D-A features that absorbs visible light in the range between 400 and 550 nm and emits fluorescence peaked at 600-620 nm, with a maximum quantum yield (QY) of 50% when dispersed (0.1-1.5 wt%) in PMMA and PC matrices. QY and lifetime investigations demonstrated that fluorescence quenching occurred with varying the TPE-AC concentration, even if the optical features were still significant even at the highest fluorophore content. Study of the LSCs' performances yielded worthy optical efficiencies of 6.7% for the TPE-AC/PC systems due to their superior light harvesting features and the compatibility of the AIEgen within the PC matrix.
Autore Pugliese
Tutti gli autori
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De Nisi F.; Francischello R.; Battisti A.; Panniello A.; Fanizza E.; Striccoli M.; Gu X.; Leung N. L. C.; Tang B. Z.; Pucci A.
Titolo volume/Rivista
RSC materials monographs
Anno di pubblicazione
2017
ISSN
1757-7128
ISBN
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Nessuna citazione
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