Abstract

Traditional shape memory polymers (SMPs) are mostly thermoresponsive and their applications in nanooptics are hindered by heat-demanding programming and recovery processes. By integrating a polyurethane-based shape memory copolymer with templating nanofabrication, reconfigurable/rewritable macroporous photonic crystals have been demonstrated. This SMP coupled with the unique macroporous structure enables unusual all-room-temperature shape memory cycles. "Cold" programming involving microscopic order-disorder transitions of the templated macropores is achieved by mechanically deforming the macroporous SMP membranes. The rapid recovery of the permanent, highly ordered photonic crystal structure from the temporary, disordered configuration can be triggered by multiple stimuli, including a large variety of vapors and solvents, heat, and microwave radiation. Importantly, the striking chromogenic effects associated with these athermal and thermal processes render a sensitive and noninvasive optical methodology for quantitatively characterizing the intriguing nanoscopic shape memory effects. Some critical parameters/mechanisms that could significantly affect the final performance of SMP-based reconfigurable photonic crystals, including strain recovery ratio, dynamics and reversibility of shape recovery, as well as capillary condensation of vapors in macropores, which plays a crucial role in vapor-triggered recovery, can be evaluated using this new optical technology.

Autore Pugliese

• Basile Vito

Tutti gli autori

• Fang Y.; Leo S.-Y.; Ni Y.; Wang J.; Wang B.; Yu L.; Dong Z.; Dai Y.; Basile V.; Taylor C.; Jiang P.

Titolo volume/Rivista

ACS applied materials & interfaces

Anno di pubblicazione

2017

ISSN

1944-8252

ISBN

Non Disponibile

Numero di citazioni Wos

Nessuna citazione

Ultimo Aggiornamento Citazioni

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Numero di citazioni Scopus

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Ultimo Aggiornamento Citazioni

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Settori ERC

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Codici ASJC

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