Influence of Chemistry on Wetting Dynamics of Nanotextured Hydrophobic Surfaces

Abstract

In this work, the role of a chemical parameter, such as the degree of fluorination, on the wetting behavior ofnanotextured hydrophobic surfaces is investigated. Texture and chemistry tuning of the surfaces has been accomplishedwith single batch radiofrequency low-pressure plasma processes. Polystyrene substrates have been textured by CF4plasma etching and subsequently covered by thin films with a tunable F-to-C ratio, obtained in discharges fed withC4F8-C2H4. Measurements of wetting dynamics reveal a regime transition from adhesive-hydrophobic to slipperysuperhydrophobic,i.e., from wet to non wet states, as the F-to-C rises at constant topography. Such achievements arestrengthened by calculation of the solid fraction of surface water contact area applying Cassie-Baxter advancing andreceding equations to water contact angle data of textured and flat reference surfaces


Autore Pugliese

Tutti gli autori

  • F. Palumbo; R. D'Agostino; R. Di Mundo

Titolo volume/Rivista

Langmuir


Anno di pubblicazione

2010

ISSN

0743-7463

ISBN

Non Disponibile


Numero di citazioni Wos

Nessuna citazione

Ultimo Aggiornamento Citazioni

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Numero di citazioni Scopus

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Ultimo Aggiornamento Citazioni

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Settori ERC

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Codici ASJC

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