Hydrophobin: Fluorosurfactant-like properties without fluorine

Abstract

The stabilization of fluorous oil droplets in aqueous environment is a critical issue in the preparation of emulsified systems for biomedical applications and in emulsion polymerization technology, due to the extreme immiscibility of aqueous and fluorous phases. We present here a detailed study on the behavior of the hydrophobin HFBI, i.e. a small natural protein endowed with exceptional surface activity, at the interface between aqueous and fluorous phases. HFBI behaves as an efficient and sustainable surfactant at remarkably low concentrations and forms a strong and elastic film at the interface between the two phases. We also show proof-of-concept experiments on the use of HFBI as a surfactant in fluorous oil/water emulsified systems and in microfluidic circuits. This journal is © The Royal Society of Chemistry 2013.


Autore Pugliese

Tutti gli autori

  • Milani R.; Monogioudi E.; Baldrighi M.; Cavallo G.; Arima V.; Marra L.; Zizzari A.; Rinaldi R.; Linder M.; Resnati G.; Metrangolo P.

Titolo volume/Rivista

Soft matter


Anno di pubblicazione

2013

ISSN

1744-6848

ISBN

Non Disponibile


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Nessuna citazione

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Settori ERC

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Codici ASJC

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