Towards highly stable aqueous dispersions of multi-walled carbon nanotubes: the effect of oxygen plasma functionalization

Abstract

In order to improve the dispersion of multi-walled carbon nanotubes (MWCNTs) in aqueous media, their surface functionalization was carried out in O2-fed low-pressure plasmas. Differently from what can be found in the literature of this field, homogeneous functionalization was achieved by generating the plasma inside vials containing the nanotube powders properly stirred. Experimental parameters, such as input power, treatment time and pressure, were varied to investigate their influence on the process efficiency. A detailed characterization of the plasma treated nanotubes, dry and in aqueous suspension, was carried out with a multi-diagnostic analytical approach, to evaluate their surface chemical properties, morphology, structural integrity and stability in the colloidal state. The plasma grafting of polar ionizable (e.g. acid) groups has been proved to successfully limit the agglomeration of MWCNTs and to produce nanotubes suspensions that are stable for one month and more in water.


Tutti gli autori

  • MANGONE A.;PALAZZO G.;GIANNOSSA L.C.;GARZIA TRULLI M.;FAVIA P.;COMPARELLI R.

Titolo volume/Rivista

Non Disponibile


Anno di pubblicazione

2017

ISSN

0021-9797

ISBN

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Numero di citazioni Wos

18

Ultimo Aggiornamento Citazioni

Non Disponibile


Numero di citazioni Scopus

18

Ultimo Aggiornamento Citazioni

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Settori ERC

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Codici ASJC

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