Spectroscopic study on imidazolium based ionic liquids: effect of alkyl chain length and anion

Abstract

Room temperature ionic liquids are currently used as functional materials in several application and their optical investigation can provide a better understanding of their physical and chemical behavior. Absorption and emission properties of imidazolium-based ILs have been attributed to the imidazolium moiety and related to the presence of energetically different aggregates. Here, time-integrated and time-resolved investigation has been carried out on 1-alkyl-3-methylimidazolium tetrafluoroborate and hexafluorophosphate ionic liquids with different chain lengths in order to probe the occurrence of energy transfer processes, and hence to disclose the presence of various states with different energy. Such a study contributes to provide relevant insight on the effect of alkyl chain and anion type on the emission characteristics, and, hence, on the presence of associated structures.


Tutti gli autori

  • AGOSTIANO A.;TRIGGIANI L.;TOMMASI R.

Titolo volume/Rivista

Non Disponibile


Anno di pubblicazione

2012

ISSN

1520-6106

ISBN

Non Disponibile


Numero di citazioni Wos

42

Ultimo Aggiornamento Citazioni

Non Disponibile


Numero di citazioni Scopus

43

Ultimo Aggiornamento Citazioni

Non Disponibile


Settori ERC

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Codici ASJC

Non Disponibile