Non-equilibrium H2 formation in the early Universe: energy exchanges, rate coefficients and spectral distortions

Abstract

Energy exchange processes play a crucial role in the early universe, affecting the thermal balance and the dynamical evolution of the primordial gas. In the present work we focus on the consequences of a non-thermal distribution of the level populations of H2: first, we determine the excitation temperatures of vibrational transitions and the non-equilibrium heat transfer; second, we compare the modifications to chemical reaction rate coefficients with respect to the values obtained assuming local thermodynamic equilibrium; and third, we compute the spectral distortions to the cosmic background radiation generated by the formation of H2 in vibrationally excited levels. We conclude that non-equilibrium processes cannot be ignored in cosmological simulations of the evolution of baryons, although their observational signatures remain below current limits of detection. New fits to the equilibrium and non-equilibrium heat transfer functions are provided.


Tutti gli autori

  • COPPOLA C.M.;LONGO S.

Titolo volume/Rivista

Non Disponibile


Anno di pubblicazione

2012

ISSN

0067-0049

ISBN

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Numero di citazioni Wos

Nessuna citazione

Ultimo Aggiornamento Citazioni

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Numero di citazioni Scopus

15

Ultimo Aggiornamento Citazioni

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Settori ERC

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Codici ASJC

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