Classification of olive oils according to geographical origin by using 1H NMR fingerprinting combined with multivariate analysis

Abstract

Authentic extravirgin olive oils from 7 different regions (Italy – 3 regions, Greece – 4 regions) have been investigated by 1H Nuclear Magnetic Resonance (NMR) fingerprinting in combination with multivariate statistical analysis. In order to cover the dominating lipid signals as well as signals from compounds of low abundance in the oil, both a simple one pulse experiment and an experiment with multiple saturation of the lipid signals was applied to each sample. Thus, the dynamic range of concentrations covered by the two experiments was of the order of 100,000 allowing for a more comprehensive NMR assessment of the samples. Monte-Carlo embedded cross-validation was used to demonstrate that a combination of principal component analysis, canonical analysis, and classification via nearest class mean can be used to predict the origin of olive oil samples from 1H NMR data. Given the rather limited number of samples tested, correct prediction probabilities of 78% were achieved with region specific correct predictions between 53% and 100%.


Autore Pugliese

Tutti gli autori

  • LONGOBARDI F.

Titolo volume/Rivista

Non Disponibile


Anno di pubblicazione

2012

ISSN

0308-8146

ISBN

Non Disponibile


Numero di citazioni Wos

72

Ultimo Aggiornamento Citazioni

Non Disponibile


Numero di citazioni Scopus

73

Ultimo Aggiornamento Citazioni

Non Disponibile


Settori ERC

Non Disponibile

Codici ASJC

Non Disponibile