One-pot synthesis of aniline derivatives from nitroarenes under mild conditions promoted by a recyclable polymer-supported palladium catalyst

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Abstract

This work describes the one-pot direct reductive amination of carbonyl compounds with nitroarenes promoted by a polymer supported palladium catalyst, in the presence of molecular hydrogen as the reductant. This methodology is applicable, with slight differences, to both aliphatic and aromatic aldehydes. The operational simplicity, the mild reaction conditions, the high yields and the good recyclability of the supported catalyst are major advantages of this method. TEM observations of the catalyst showed that the active species are palladium nanoparticles having a size distribution centered at 5 nm within the polymeric support. (C) 2011 Elsevier B.V. All rights reserved.

Autore Pugliese

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  • DELL'ANNA Maria Michela , MASTRORILLI Pietro , RIZZUTI Antonino , Leonelli Cristina

Titolo volume/Rivista

APPLIED CATALYSIS A: GENERAL

Anno di pubblicazione

2011

ISSN

0926-860X

ISBN

Non Disponibile

Numero di citazioni Wos

Nessuna citazione

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Non Disponibile

Numero di citazioni Scopus

32

Ultimo Aggiornamento Citazioni

2017-04-22 03:20:59

Settori ERC

Non Disponibile

Codici ASJC

Non Disponibile