Molecular Physics of Elementary Processes Relevant to Hypersonics: Electron-Molecule Collisions
Abstract
Non-resonant, electron-impact, vibro-electronic excitation cross sections, involving vibrationally excited N2 molecules, to the mixed valence-Rydberg b,c,o 1Πu and b′,c′,e′ 1Σu+ singlet states are presented. These cross sections are calculated using the so-called similarity approach, accounting for the vibronic coupling among excited states, and compared with the experiments and different theoretical calculations. New cross sections for the electron-impact resonant vibrational excitation of CO2 molecule are calculated, for the symmetric stretching mode, as a function of the incident electron energy and for the transitions (υi , 0,0)→(υf , 0,0) with υi = 0,1,2 and for some selected value of υf in the interval υi ≤ υf ≤10. A resonance potential curve and associated widths are calculated using the R-matrix method. Rate coefficients, calculated by assuming a Maxwellian electron energy distribution function, are also presented for the same (υi,0,0)→(υf,0,0) transitions. Electron-impact cross sections and rate coefficients for resonant vibrational excitations involving the diatomic species N2, NO, CO, O2 and H2, for multi-quantic and mono-quantic transitions, are reviewed along with the cross sections and rates for the process of the dissociative electron attachment to H2 molecule, involving a Rydberg excited resonant state of the H2- ion.
Autore Pugliese
Tutti gli autori
-
Celiberto R , Laporta V , Laricchiuta A , Tennyson J , and Wadehra JM
Titolo volume/Rivista
THE OPEN PLASMA PHYSICS JOURNAL
Anno di pubblicazione
2014
ISSN
1876-5343
ISBN
Non Disponibile
Numero di citazioni Wos
Nessuna citazione
Ultimo Aggiornamento Citazioni
Non Disponibile
Numero di citazioni Scopus
Non Disponibile
Ultimo Aggiornamento Citazioni
Non Disponibile
Settori ERC
Non Disponibile
Codici ASJC
Non Disponibile
Condividi questo sito sui social