Zinc oxide nanostructured layers for gas sensing applications

Abstract

Various kinds of zinc oxide (ZnO) nanostructures, such as columns, pencils, hexagonal pyramids, hexagonal hierarchical structures, as well as smooth and rough films, were grown by pulsed laser deposition using KrF and ArF excimer lasers, without use of any catalyst. ZnO films were deposited at substrate temperatures from 500 to 700°C and oxygen background pressures of 1, 5, 50, and 100 Pa. Quite different morphologies of the deposited films were observed using scanning electron microscopy when different laser wavelengths (248 or 193 nm) were used to ablate the bulk ZnO target. Photoluminescence studies were performed at different temperatures (down to 7 K). The gas sensing properties of the different nanostructures were tested against low concentrations of NO 2. The variation in the photoluminescence emission of the films when exposed to NO 2 was used as transduction mechanism to reveal the presence of the gas. The nanostructured films with higher surface-to-volume ratio and higher total surface available for gas adsorption presented higher responses, detecting NO 2 concentrations down to 3 ppm at room temperature


Tutti gli autori

  • Caricato A.P. , Cretí A. , Luches A. , Lomascolo M. , Martino M. , Rella R. , Valerini D.

Titolo volume/Rivista

LASER PHYSICS


Anno di pubblicazione

2011

ISSN

1054-660X

ISBN

Non Disponibile


Numero di citazioni Wos

2

Ultimo Aggiornamento Citazioni

27/04/2018


Numero di citazioni Scopus

2

Ultimo Aggiornamento Citazioni

28/04/2018


Settori ERC

Non Disponibile

Codici ASJC

Non Disponibile