Abstract

Novel photopolymerizable nanocomposite formulations, able to photopolymerize with a dual curing mechanism (cationic and radical), were developed, characterized and used in the stereolithography (SL) process for the construction of 3D objects with a very simple geometry. The influence of the presence of organically modified montmorillonite (OM) nanoparticles on the reactivity of the photopolymerizable liquid mixtures was firstly analyzed, as function of the amount of nanofiller, by photocalorimetric analysis (p-DSC). The basal distance of OM before and after mixing with the photocurable formulation was characterized by X-ray diffraction. Composites with higher content of OM show an intercalated structure. An exfoliated structurewas instead observed in the compositeswith the lowestOMcontent, after photocuring in the SL apparatus. These results were also confirmed by the morphological analysis performed by SEM. The glass transition temperature of nanocomposites, photocured by stereolithography, was finally measured by TMA and DSC techniques, confirming that the photocurable formulation loaded with the lowest amount of OM presents improved properties than the unloaded formulation.

Autore Pugliese

• Esposito Corcione Carola

Tutti gli autori

• C. Esposito Corcione , R. Striani , F. Montagna , D. Cannoletta

Titolo volume/Rivista

POLYMERS FOR ADVANCED TECHNOLOGIES

Anno di pubblicazione

2015

ISSN

1042-7147

ISBN

Non Disponibile

Numero di citazioni Wos

9

Ultimo Aggiornamento Citazioni

28/04/2018

Numero di citazioni Scopus

9

Ultimo Aggiornamento Citazioni

28/04/2018

Settori ERC

Non Disponibile

Codici ASJC

Non Disponibile