Abstract

Ni-cerium oxide coatings were electrodeposited from particle-free aqueous baths containing NiCl2.6H2O and CeCl3.7H2O. The mechanism of deposition was studied systematically by a combination of voltammetric, in situ spectoelectrochemical (visible reflectivity VRS, surface Raman spectroscopy SRS), ex situ spectroscopic (spectroscopic ellipsometry SE) methods, as well as by SEM imaging; yielding details on the steps of the composite formation process. Time- and potential-dependent ERS data were interpreted on the basis of an optical model, accounting for the formation of metal and ceramic phases and corresponding relative distribution and morphology. In the ERS curves measured with the pure Ni and Ce-containing solutions, the value of reflectivity drops sharply when the potential is lower than ca. -0.9 V. The ERS curves measured in the Ce-containing solutions exhibit a second drop when the potential is lower than ca. -1.1V while, instead, for pure Ni solution an increase in reflectivity is observed. According to the proposed optical model, the drop found in the reflectivity transient can be explained with the nucleation of Ni on the Cu substrate, while the second one measured with Ce-containing solutions is due to secondary nucleation of Ni. The results showed that the deposition processes of Ni and Ni-cerium oxide can be divided into 2 and 4 stages respectively. (i) In the case on Ni: nucleation and 3D growth, accompanied by roughening; (ii) as far as Ni-cerium oxide is concerned: nucleation, formation of cerium oxide, secondary nucleation and 3D growth and roughening.

Autore Pugliese

• Bozzini Benedetto , Mele Claudio

Tutti gli autori

• H. Hassannejad , C. Mele , T. Shahrabi , B. Bozzini

Titolo volume/Rivista

JOURNAL OF SOLID STATE ELECTROCHEMISTRY

Anno di pubblicazione

2012

ISSN

1432-8488

ISBN

Non Disponibile

Numero di citazioni Wos

6

Ultimo Aggiornamento Citazioni

26/04/2018

Numero di citazioni Scopus

6

Ultimo Aggiornamento Citazioni

26/04/2018

Settori ERC

Non Disponibile

Codici ASJC

Non Disponibile